如题所述
that 既可以用于指人，也可以用于指物。在从句中作主语或宾语，作主语时不可省略，作宾语可省略。例如：
Mary likes music that is quiet and gentle.玛丽喜欢轻柔的音乐。（that作主语）
2.which用于指物，在句中作主语或宾语，作主语不可省略，作宾语可省略。例如：
The building which stands near the train station is a supermarket.位于火车站附近的那座大楼是一家超市。（作主语）
The film （which） we saw last night was wonderful. 我们昨天晚上看的那部电影很好看。（作宾语）
关系词只能用that的情况：
a. 先行词被序数词或形容词最高级所修饰，或本身是序数词、基数词、形容词最高级时，只能用that，而不用which.例如：
He was the first person that passed the exam. 他是第一个通过考试的人。
b.被修饰的先行词为all， any， much， many， everything， anything， none， the one等不定代词时，只能用that，而不用which.例如：
Is there anything that you want to buy in the shop？ 你在商店里有什么东西要买吗？
c.先行词被the only， the very， the same， the last， little， few 等词修饰时，只能用that，而不用which.例如：
This is the same bike that I lost.这就是我丢的那辆自行车。
d. 先行词里同时含有人或物时，只能用that， 而不用which.例如：
I can remember well the persons and some pictures that I saw in the room.我能清楚记得我在那个房间所见到的人和一些照片。
e.以who或which引导的特殊疑问句，为避免重复，只能用that.例如：
Who is the girl that is crying？ 正在哭泣的那个女孩是谁？
f.主句是there be 结构，修饰主语的定语从句用that，而不用which.例如：
There is a book on the desk that belongs to Tom. 桌子上那本书是汤姆的。
关系词只能用which，而不用that 的情况：
a.先行词为that， those时，用which， 而不用that.例如：
What’s that which is under the desk？ 在桌子底下的那些东西是什么？
b.关系代词前有介词时，一般用which，而不用that.例如：
This is the room in which he lives. 这是他居住的房间。
c.引导非限制性定语从句，用which， 而不用that.例如：
Mary likes music that is quiet and gentle.玛丽喜欢轻柔的音乐。（that作主语）
2.which用于指物，在句中作主语或宾语，作主语不可省略，作宾语可省略。例如：
The building which stands near the train station is a supermarket.位于火车站附近的那座大楼是一家超市。（作主语）
The film （which） we saw last night was wonderful. 我们昨天晚上看的那部电影很好看。（作宾语）
关系词只能用that的情况：
a. 先行词被序数词或形容词最高级所修饰，或本身是序数词、基数词、形容词最高级时，只能用that，而不用which.例如：
He was the first person that passed the exam. 他是第一个通过考试的人。
b.被修饰的先行词为all， any， much， many， everything， anything， none， the one等不定代词时，只能用that，而不用which.例如：
Is there anything that you want to buy in the shop？ 你在商店里有什么东西要买吗？
c.先行词被the only， the very， the same， the last， little， few 等词修饰时，只能用that，而不用which.例如：
This is the same bike that I lost.这就是我丢的那辆自行车。
d. 先行词里同时含有人或物时，只能用that， 而不用which.例如：
I can remember well the persons and some pictures that I saw in the room.我能清楚记得我在那个房间所见到的人和一些照片。
e.以who或which引导的特殊疑问句，为避免重复，只能用that.例如：
Who is the girl that is crying？ 正在哭泣的那个女孩是谁？
f.主句是there be 结构，修饰主语的定语从句用that，而不用which.例如：
There is a book on the desk that belongs to Tom. 桌子上那本书是汤姆的。
关系词只能用which，而不用that 的情况：
a.先行词为that， those时，用which， 而不用that.例如：
What’s that which is under the desk？ 在桌子底下的那些东西是什么？
b.关系代词前有介词时，一般用which，而不用that.例如：
This is the room in which he lives. 这是他居住的房间。
c.引导非限制性定语从句，用which， 而不用that.例如：
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第1个回答 2013-11-28
which, that 区别如下。as I had expected是作状语
它们所代替的先行词是事物的名词或代词，在从句中可作主语、宾语等，例如：
A prosperity which / that had never been seen before appears in the countryside.（which / that在句中作宾语）
The package (which / that) you are carrying is about to come unwrapped. (which / that在句中作宾语)
关系代词that和which 都可以指物，that 和Who 都可以指人，其用法区别：
1）不用that的情况
a) 在引导非限定性定语从句时
(错) The tree, that is four hundred years old, is very famous here.
b) 介词后不能用
We depend on the land from which we get our food.
c)多用who 的情况
①关系代词在从句中做主语
A friend who helps you in time of need is a real friend .
②先行词为those , people 时
Those who were either fools or unfit for their offices could not see the cloth .
③先行词为all, anyone , ones , one 指人时
One who doesn’t work hard will never succeed in his work .
④在There be句型中
There is a stranger who wants to see you .
⑤在被分隔的定语从句中
A new teacher will come tomorrow who will teach you German .
⑥在有两个定语从句的句子中，其一用who,其二用that,但若先行词后接两个以上的并列定语从句时，后一个必须重复前一个关系代词。
The student who was praised at the meeting is the monitor that is very modest and studies very hard .
There is a teacher who is always ready to help others and who enjoys what he does .
2) 只能用that作为定语从句的关系代词的情况
a) 在不定代词，如：anything, nothing, everything, all, much, few, any, little等作先行词时，只用that，不用which。
All that is needed is a supply of oil.
Finally, the thief handed everything that he had stolen to the police.
b) 先行词有the only, the very, the just修饰时，只用that。
He is the very man that helped the girl out of the water .
c) 先行词为序数词(the last)、数词、形容词最高级时，只用that。.
The first English book that I read was “The Prince and the Pauper” by Mark Twin .
d) 先行词既有人，又有物时。
He talked about the teachers and schools that he visited .
e)当主句是以who 或which 开始的特殊疑问句时，用that 以避免重复。
Who is the person that is standing at the gate .
f)关系代词在从句中做表语
它们所代替的先行词是事物的名词或代词，在从句中可作主语、宾语等，例如：
A prosperity which / that had never been seen before appears in the countryside.（which / that在句中作宾语）
The package (which / that) you are carrying is about to come unwrapped. (which / that在句中作宾语)
关系代词that和which 都可以指物，that 和Who 都可以指人，其用法区别：
1）不用that的情况
a) 在引导非限定性定语从句时
(错) The tree, that is four hundred years old, is very famous here.
b) 介词后不能用
We depend on the land from which we get our food.
c)多用who 的情况
①关系代词在从句中做主语
A friend who helps you in time of need is a real friend .
②先行词为those , people 时
Those who were either fools or unfit for their offices could not see the cloth .
③先行词为all, anyone , ones , one 指人时
One who doesn’t work hard will never succeed in his work .
④在There be句型中
There is a stranger who wants to see you .
⑤在被分隔的定语从句中
A new teacher will come tomorrow who will teach you German .
⑥在有两个定语从句的句子中，其一用who,其二用that,但若先行词后接两个以上的并列定语从句时，后一个必须重复前一个关系代词。
The student who was praised at the meeting is the monitor that is very modest and studies very hard .
There is a teacher who is always ready to help others and who enjoys what he does .
2) 只能用that作为定语从句的关系代词的情况
a) 在不定代词，如：anything, nothing, everything, all, much, few, any, little等作先行词时，只用that，不用which。
All that is needed is a supply of oil.
Finally, the thief handed everything that he had stolen to the police.
b) 先行词有the only, the very, the just修饰时，只用that。
He is the very man that helped the girl out of the water .
c) 先行词为序数词(the last)、数词、形容词最高级时，只用that。.
The first English book that I read was “The Prince and the Pauper” by Mark Twin .
d) 先行词既有人，又有物时。
He talked about the teachers and schools that he visited .
e)当主句是以who 或which 开始的特殊疑问句时，用that 以避免重复。
Who is the person that is standing at the gate .
f)关系代词在从句中做表语
第2个回答 2013-11-28
非限制定语从句中，就是一个句子有逗号，从句是定语从句的那种像，He said it is very cheap,which I do not agree with.本回答被网友采纳
